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On the σ-complex character of bis(gallyl)/digallane transition metal species
σ-complexes of homoatomic E–E bonds are key intermediates in catalytically relevant oxidative addition reactions, but are as yet unknown for the group 13 elements. Here, stable species best described as σ-complexes of a 1,2-dichlorodigallane derivative with Ni and Pd are reported. They are readily a...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10583741/ https://www.ncbi.nlm.nih.gov/pubmed/37860650 http://dx.doi.org/10.1039/d3sc03772j |