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Rh(II)-Catalyzed Si–H Insertion with Nosyl-hydrazone-Protected Aryl Donor Diazo Compounds

[Image: see text] Dirhodium(II,II) paddlewheel catalysts were evaluated in silyl-hydrogen insertion reactions of aryl diazo compounds generated from o-nosyl hydrazones. The high reactivity of aryl diazo compounds necessitates their in situ generation from sulfonyl-protected hydrazones. Herein, we de...

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Detalles Bibliográficos
Autores principales: Abshire, Anthony, Ogunyemi, Bukola, Darko, Ampofo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10586302/
https://www.ncbi.nlm.nih.gov/pubmed/37867650
http://dx.doi.org/10.1021/acsomega.3c03519