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Origin of Long-Range Hyperfine Couplings in the EPR Spectra of 2,2,5,5-Tetraethylpyrrolidine-1-oxyls

[Image: see text] Cyclic nitroxides with several bulky alkyl substituents adjacent to the nitroxide group are known to demonstrate a much higher stability to bioreduction than their tetramethyl analogues. Among these so-called “sterically shielded” nitroxides, the pyrrolidine derivatives are the mos...

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Detalles Bibliográficos
Autores principales: Polienko, Yuliya F., Dobrynin, Sergey A., Lomanovich, Konstantin A., Brovko, Anastasiya O., Bagryanskaya, Elena G., Kirilyuk, Igor A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10586448/
https://www.ncbi.nlm.nih.gov/pubmed/37867656
http://dx.doi.org/10.1021/acsomega.3c06090