Cargando…

Mechanistic insights into excited-state palladium catalysis for C–S bond formations and dehydrogenative sulfonylation of amines

Photocatalytic selective C(sp(3))–H activation/cross-coupling reactions are appealing in organic synthesis. In this manuscript, we describe the development of photoexcited-state Pd-catalyzed dehydrogenative β-sulfonylation reactions using amines and aryl sulfonyl chlorides via intermolecular hydroge...

Descripción completa

Detalles Bibliográficos
Autores principales: Muralirajan, Krishnamoorthy, Kancherla, Rajesh, Maity, Bholanath, Karuthedath, Safakath, Laquai, Frédéric, Cavallo, Luigi, Rueping, Magnus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10587301/
https://www.ncbi.nlm.nih.gov/pubmed/37857662
http://dx.doi.org/10.1038/s41467-023-42392-2