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Actinide-lanthanide single electron metal-metal bond formed in mixed-valence di-metallofullerenes

Understanding metal-metal bonding involving f-block elements has been a challenging goal in chemistry. Here we report a series of mixed-valence di-metallofullerenes, ThDy@C(2n) (2n = 72, 76, 78, and 80) and ThY@C(2n) (2n = 72 and 78), which feature single electron actinide-lanthanide metal-metal bon...

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Detalles Bibliográficos
Autores principales: Yan, Yingjing, Abella, Laura, Sun, Rong, Fang, Yu-Hui, Roselló, Yannick, Shen, Yi, Jin, Meihe, Rodríguez-Fortea, Antonio, de Graaf, Coen, Meng, Qingyu, Yao, Yang-Rong, Echegoyen, Luis, Wang, Bing-Wu, Gao, Song, Poblet, Josep M., Chen, Ning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10589252/
https://www.ncbi.nlm.nih.gov/pubmed/37863887
http://dx.doi.org/10.1038/s41467-023-42165-x