Cargando…
Actinide-lanthanide single electron metal-metal bond formed in mixed-valence di-metallofullerenes
Understanding metal-metal bonding involving f-block elements has been a challenging goal in chemistry. Here we report a series of mixed-valence di-metallofullerenes, ThDy@C(2n) (2n = 72, 76, 78, and 80) and ThY@C(2n) (2n = 72 and 78), which feature single electron actinide-lanthanide metal-metal bon...
Autores principales: | Yan, Yingjing, Abella, Laura, Sun, Rong, Fang, Yu-Hui, Roselló, Yannick, Shen, Yi, Jin, Meihe, Rodríguez-Fortea, Antonio, de Graaf, Coen, Meng, Qingyu, Yao, Yang-Rong, Echegoyen, Luis, Wang, Bing-Wu, Gao, Song, Poblet, Josep M., Chen, Ning |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10589252/ https://www.ncbi.nlm.nih.gov/pubmed/37863887 http://dx.doi.org/10.1038/s41467-023-42165-x |
Ejemplares similares
-
Small endohedral metallofullerenes: exploration of the structure and growth mechanism in the Ti@C(2n) (2n = 26–50) family
por: Mulet-Gas, Marc, et al.
Publicado: (2015) -
U(2)N@I(h)(7)-C(80): fullerene cage encapsulating an unsymmetrical U(iv)[double bond, length as m-dash]N[double bond, length as m-dash]U(v) cluster
por: Li, Xiaomeng, et al.
Publicado: (2020) -
Are
U–U Bonds Inside Fullerenes Really Unwilling
Bonds?
por: Moreno-Vicente, Antonio, et al.
Publicado: (2023) -
Structurally Defined Water‐Soluble Metallofullerene Derivatives towards Biomedical Applications
por: Li, Yanbang, et al.
Publicado: (2022) -
Nanosized Gadolinium and Uranium—Two Representatives
of High-Reactivity Lanthanide and Actinide Metal Nanoparticles
por: Schöttle, Christian, et al.
Publicado: (2017)