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Single—Not Double—3D-Aromaticity in an Oxidized Closo Icosahedral Dodecaiodo-Dodecaborate Cluster

[Image: see text] 3D-aromatic molecules with (distorted) tetrahedral, octahedral, or spherical structures are much less common than typical 2D-aromatic species or even 2D-aromatic-in-3D systems. Closo boranes, [B(n)H(n)](2–) (5 ≤ n ≤ 14) and carboranes are examples of compounds that are singly 3D-ar...

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Detalles Bibliográficos
Autores principales: Poater, Jordi, Escayola, Sílvia, Poater, Albert, Teixidor, Francesc, Ottosson, Henrik, Viñas, Clara, Solà, Miquel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10591335/
https://www.ncbi.nlm.nih.gov/pubmed/37728951
http://dx.doi.org/10.1021/jacs.3c07335