Thermal Decomposition of 2- and 4-Iodobenzyl Iodide Yields Fulvenallene and Ethynylcyclopentadienes: A Joint Threshold Photoelectron and Matrix Isolation Spectroscopic Study

[Image: see text] The thermal decomposition of 2- and 4-iodobenzyl iodide at high temperatures was investigated by mass-selective threshold photoelectron spectroscopy (ms-TPES) in the gas phase, as well as by matrix isolation infrared spectroscopy in cryogenic matrices. Scission of the benzylic C–I...

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Detalles Bibliográficos
Autores principales: Saraswat, Mayank, Portela-Gonzalez, Adrian, Karir, Ginny, Mendez-Vega, Enrique, Sander, Wolfram, Hemberger, Patrick
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10591508/
https://www.ncbi.nlm.nih.gov/pubmed/37734109
http://dx.doi.org/10.1021/acs.jpca.3c04688

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10591508/
https://www.ncbi.nlm.nih.gov/pubmed/37734109
http://dx.doi.org/10.1021/acs.jpca.3c04688

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