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Thermal Decomposition of 2- and 4-Iodobenzyl Iodide Yields Fulvenallene and Ethynylcyclopentadienes: A Joint Threshold Photoelectron and Matrix Isolation Spectroscopic Study
[Image: see text] The thermal decomposition of 2- and 4-iodobenzyl iodide at high temperatures was investigated by mass-selective threshold photoelectron spectroscopy (ms-TPES) in the gas phase, as well as by matrix isolation infrared spectroscopy in cryogenic matrices. Scission of the benzylic C–I...
Autores principales: | Saraswat, Mayank, Portela-Gonzalez, Adrian, Karir, Ginny, Mendez-Vega, Enrique, Sander, Wolfram, Hemberger, Patrick |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10591508/ https://www.ncbi.nlm.nih.gov/pubmed/37734109 http://dx.doi.org/10.1021/acs.jpca.3c04688 |
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