Catalytic C–H Trifluoromethylation of Arenes and Heteroarenes via Visible Light Photoexcitation of a Co(III)–CF(3) Complex

[Image: see text] A cobalt photocatalyst for direct trifluoromethylation of (hetero)arene C(sp(2))–H bonds is described and shown to operate via visible light activation of a Co–CF(3) intermediate, which functions as a combined chromophore and organometallic reaction center. Chemical oxidations of p...

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Detalles Bibliográficos
Autores principales: Kuehner, Christopher S., Hill, Andrew G., Harris, Caleb F., Owens, Christian A., Bacsa, John, Soper, Jake D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594583/
https://www.ncbi.nlm.nih.gov/pubmed/37881792
http://dx.doi.org/10.1021/acscatal.3c03832

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594583/
https://www.ncbi.nlm.nih.gov/pubmed/37881792
http://dx.doi.org/10.1021/acscatal.3c03832

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