Cargando…

Experimental and Theoretical Analysis of the Thiol-Promoted Fragmentation of 2-Halo-3-tosyl-oxanorbornadienes

[Image: see text] 2-Halo-3-tosyl-oxanorbornadienes are able to accept two thiol molecules through an initial nucleophilic substitution, giving isolable oxabicyclic thiovinyl sulfones that, subsequently, can react with a second thiol molecule via thio-Michael addition. The resulting oxanorbornenic th...

Descripción completa

Detalles Bibliográficos
Autores principales: Carranza, Marina, Carmona, Ana T., Navo, Claudio D., Robina, Inmaculada, Fratta, Simone, Newburn, Carlos, Jiménez-Osés, Gonzalo, Moreno-Vargas, Antonio J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594659/
https://www.ncbi.nlm.nih.gov/pubmed/37815231
http://dx.doi.org/10.1021/acs.orglett.3c02548