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Experimental and Theoretical Analysis of the Thiol-Promoted Fragmentation of 2-Halo-3-tosyl-oxanorbornadienes

[Image: see text] 2-Halo-3-tosyl-oxanorbornadienes are able to accept two thiol molecules through an initial nucleophilic substitution, giving isolable oxabicyclic thiovinyl sulfones that, subsequently, can react with a second thiol molecule via thio-Michael addition. The resulting oxanorbornenic th...

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Detalles Bibliográficos
Autores principales:	Carranza, Marina, Carmona, Ana T., Navo, Claudio D., Robina, Inmaculada, Fratta, Simone, Newburn, Carlos, Jiménez-Osés, Gonzalo, Moreno-Vargas, Antonio J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594659/ https://www.ncbi.nlm.nih.gov/pubmed/37815231 http://dx.doi.org/10.1021/acs.orglett.3c02548

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