Adamantylidenecarbene: Photochemical Generation, Trapping, and Theoretical Studies

[Image: see text] Photolysis of 1-(2-adamantylidene)-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene in benzene (or benzene-d(6)) at ambient temperature produces adamantylidenecarbene. The carbene undergoes dimerization to a cumulene and may also be trapped in a stereospecific fashion by cis- and trans-4...

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Detalles Bibliográficos
Autores principales: Roth, Alexander D., Wamsley, Christine E., Haynes, Sarah M., Thamattoor, Dasan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594661/
https://www.ncbi.nlm.nih.gov/pubmed/37768172
http://dx.doi.org/10.1021/acs.joc.3c01399

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594661/
https://www.ncbi.nlm.nih.gov/pubmed/37768172
http://dx.doi.org/10.1021/acs.joc.3c01399

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