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Adamantylidenecarbene: Photochemical Generation, Trapping, and Theoretical Studies
[Image: see text] Photolysis of 1-(2-adamantylidene)-1a,9b-dihydro-1H-cyclopropa[l]phenanthrene in benzene (or benzene-d(6)) at ambient temperature produces adamantylidenecarbene. The carbene undergoes dimerization to a cumulene and may also be trapped in a stereospecific fashion by cis- and trans-4...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10594661/ https://www.ncbi.nlm.nih.gov/pubmed/37768172 http://dx.doi.org/10.1021/acs.joc.3c01399 |