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Anaerobic photoinduced Cu(0/I)-mediated Glaser coupling in a radical pathway
The reaction mechanism of the historic copper-catalyzed Glaser coupling has been debated to be based on redox cycles of Cu ions in specific oxidation states or on a radical mechanism based on Cu(0)/Cu(I). Here, the authors demonstrate two coexisting Glaser coupling pathways which can be differentiat...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598264/ https://www.ncbi.nlm.nih.gov/pubmed/37875487 http://dx.doi.org/10.1038/s41467-023-42602-x |