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Anaerobic photoinduced Cu(0/I)-mediated Glaser coupling in a radical pathway

The reaction mechanism of the historic copper-catalyzed Glaser coupling has been debated to be based on redox cycles of Cu ions in specific oxidation states or on a radical mechanism based on Cu(0)/Cu(I). Here, the authors demonstrate two coexisting Glaser coupling pathways which can be differentiat...

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Detalles Bibliográficos
Autores principales: Zhang, Siqi, Zhao, Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598264/
https://www.ncbi.nlm.nih.gov/pubmed/37875487
http://dx.doi.org/10.1038/s41467-023-42602-x