Enhancement of Reactivity of a Ru(IV)–Oxo Complex in Oxygen-Atom-Transfer Catalysis by Hydrogen-Bonding with Amide Moieties in the Second Coordination Sphere

[Image: see text] We have synthesized and characterized a Ru(II)–OH(2) complex (2), which has a pentadentate ligand with two pivalamide groups as bulky hydrogen-bonding (HB) moieties in the second coordination sphere (SCS). Complex 2 exhibits a coordination equilibrium through the coordination of on...

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Detalles Bibliográficos
Autores principales: Ishizuka, Tomoya, Kogawa, Taichi, Ogawa, Chisato, Kotani, Hiroaki, Shiota, Yoshihito, Yoshizawa, Kazunari, Kojima, Takahiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598587/
https://www.ncbi.nlm.nih.gov/pubmed/37885582
http://dx.doi.org/10.1021/jacsau.3c00377

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598587/
https://www.ncbi.nlm.nih.gov/pubmed/37885582
http://dx.doi.org/10.1021/jacsau.3c00377

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