Synthesis and Magnetic Properties of the Multiferroic [C(NH(2))(3)]Cr(HCOO)(3) Metal–Organic Framework: The Role of Spin–Orbit Coupling and Jahn–Teller Distortions

[Image: see text] We report for the first time the synthesis of [C(NH(2))(3)]Cr(HCOO)(3) stabilizing Cr(2+) in formate perovskite, which adopts a polar structure and orders magnetically below 8 K. We discuss in detail the magnetic properties and their coupling to the crystal structure based on first...

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Detalles Bibliográficos
Autores principales: Yananose, Kunihiro, Clark, Ewan R., Saines, Paul J., Barone, Paolo, Stroppa, Alessandro, Yu, Jaejun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598855/
https://www.ncbi.nlm.nih.gov/pubmed/37819728
http://dx.doi.org/10.1021/acs.inorgchem.3c02557

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598855/
https://www.ncbi.nlm.nih.gov/pubmed/37819728
http://dx.doi.org/10.1021/acs.inorgchem.3c02557

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