Pyrrole-Based Ti(III) and Ti(IV) PNP Pincer Complexes: Insertion of Ketones into the Ti(IV)-Phosphorus Bond

[Image: see text] The synthesis, characterization, and reactivity of pyrrole-based Ti(III) and Ti(IV) PNP pincer complexes are described. [P(NH)P-iPr] (1) reacts with [TiCl(4)(THF)(2)] at room temperature in the presence of NEt(3) to afford the Ti(IV) complex [Ti(PNP(iPr))(Cl)(3)]. This complex reac...

Descripción completa

Detalles Bibliográficos
Autores principales: Tomsu, Gerald, Stöger, Berthold, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598877/
https://www.ncbi.nlm.nih.gov/pubmed/37886626
http://dx.doi.org/10.1021/acs.organomet.3c00327

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598877/
https://www.ncbi.nlm.nih.gov/pubmed/37886626
http://dx.doi.org/10.1021/acs.organomet.3c00327

Ejemplares similares