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Pyrrole-Based Ti(III) and Ti(IV) PNP Pincer Complexes: Insertion of Ketones into the Ti(IV)-Phosphorus Bond
[Image: see text] The synthesis, characterization, and reactivity of pyrrole-based Ti(III) and Ti(IV) PNP pincer complexes are described. [P(NH)P-iPr] (1) reacts with [TiCl(4)(THF)(2)] at room temperature in the presence of NEt(3) to afford the Ti(IV) complex [Ti(PNP(iPr))(Cl)(3)]. This complex reac...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598877/ https://www.ncbi.nlm.nih.gov/pubmed/37886626 http://dx.doi.org/10.1021/acs.organomet.3c00327 |