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Unexpected Redox Chemistry of P∩N- and As∩N-Rhenium(I) Tricarbonyl Complexes in the Presence of CO(2) Acting as an Acid

[Image: see text] This study reports on Re tricarbonyl complexes bearing 8-(diphenylphosphanyl)quinoline, P∩N, and 8-(diphenylarsanyl)quinoline, As∩N, as bidendate ligands. We studied the reactivity of these complexes in comparison with fac-Re(N∩N)(CO)(3)Cl (with N∩N = 2,2′-bipyridine or 4,4′-dimeth...

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Detalles Bibliográficos
Autores principales: Ertl, Martin, Monkowius, Uwe, Oppelt, Kerstin T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598882/
https://www.ncbi.nlm.nih.gov/pubmed/37800962
http://dx.doi.org/10.1021/acs.inorgchem.3c02925