Iron(II)-Catalyzed Activation of Si–N and Si–O Bonds Using Hydroboranes

[Image: see text] We report the activation and functionalization of Si–N bonds with pinacol borane catalyzed by a three-coordinate iron(II) β-diketiminate complex. The reactions proceed via the mild activation of silazanes to yield useful hydrosilanes and aminoboranes. The reaction is studied by kin...

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Detalles Bibliográficos
Autores principales: Farcaş-Johnson, Mirela A., Gasperini, Danila, King, Andrew K., Mohan, Sakshi, Barrett, Adam N., Lau, Samantha, Mahon, Mary F., Sarazin, Yann, Kyne, Sara H., Webster, Ruth L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598884/
https://www.ncbi.nlm.nih.gov/pubmed/37886624
http://dx.doi.org/10.1021/acs.organomet.3c00339

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10598884/
https://www.ncbi.nlm.nih.gov/pubmed/37886624
http://dx.doi.org/10.1021/acs.organomet.3c00339

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