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A stronger acceptor decreases the rates of charge transfer: ultrafast dynamics and on/off switching of charge separation in organometallic donor–bridge–acceptor systems

To unravel the role of driving force and structural changes in directing the photoinduced pathways in donor–bridge–acceptor (DBA) systems, we compared the ultrafast dynamics in novel DBAs which share a phenothiazine (PTZ) electron donor and a Pt(ii) trans-acetylide bridge (–C[triple bond, length as...

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Detalles Bibliográficos
Autores principales: Auty, Alexander J., Scattergood, Paul A., Keane, Theo, Cheng, Tao, Wu, Guanzhi, Carson, Heather, Shipp, James, Sadler, Andrew, Roseveare, Thomas, Sazanovich, Igor V., Meijer, Anthony J. H. M., Chekulaev, Dimitri, Elliot, Paul I. P., Towrie, Mike, Weinstein, Julia A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10599469/
https://www.ncbi.nlm.nih.gov/pubmed/37886100
http://dx.doi.org/10.1039/d2sc06409j