Regioselective Electrophilic Addition to Propargylic B(MIDA)s Enabled by β‐Boron Effect

Electrophilic addition reaction to alkynes is of fundamental importance in organic chemistry, yet the regiocontrol when reacting with unsymmetrical 1,2‐dialkyl substituted alkynes is often problematic. Herein, it is demonstrated that the rarely recognized β‐boron effect can confer a high level of si...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Yin, Chen, Zhi‐Hao, Lin, Shuang, Liu, Yuan, Qian, Jiasheng, Li, Qingjiang, Huang, Zhi‐Shu, Wang, Honggen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10602563/
https://www.ncbi.nlm.nih.gov/pubmed/37632709
http://dx.doi.org/10.1002/advs.202304282

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10602563/
https://www.ncbi.nlm.nih.gov/pubmed/37632709
http://dx.doi.org/10.1002/advs.202304282

Ejemplares similares