The Nature of the Chemical Bonds of High-Valent Transition–Metal Oxo (M=O) and Peroxo (MOO) Compounds: A Historical Perspective of the Metal Oxyl–Radical Character by the Classical to Quantum Computations

This review article describes a historical perspective of elucidation of the nature of the chemical bonds of the high-valent transition metal oxo (M=O) and peroxo (M-O-O) compounds in chemistry and biology. The basic concepts and theoretical backgrounds of the broken-symmetry (BS) method are revisit...

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Detalles Bibliográficos
Autores principales: Yamaguchi, Kizashi, Isobe, Hiroshi, Shoji, Mitsuo, Kawakami, Takashi, Miyagawa, Koichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10609222/
https://www.ncbi.nlm.nih.gov/pubmed/37894598
http://dx.doi.org/10.3390/molecules28207119

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10609222/
https://www.ncbi.nlm.nih.gov/pubmed/37894598
http://dx.doi.org/10.3390/molecules28207119

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