Ring-Opening Reaction of 1-Phospha-2-Azanorbornenes via P-N Bond Cleavage and Reversibility Studies

The reactive P-N bond in 1-phospha-2-azanorbornenes is readily cleaved by simple alcohols to afford P-chiral 2,3-dihydrophosphole derivatives as a racemic mixture. The isolation of the products was not possible due to the reversibility of the reaction, which could, however, be stopped by sulfurizati...

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Detalles Bibliográficos
Autores principales: Ramazanova, Kyzgaldak, Müller, Anna Karina, Lönnecke, Peter, Hollóczki, Oldamur, Kirchner, Barbara, Hey-Hawkins, Evamarie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10609391/
https://www.ncbi.nlm.nih.gov/pubmed/37894642
http://dx.doi.org/10.3390/molecules28207163

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10609391/
https://www.ncbi.nlm.nih.gov/pubmed/37894642
http://dx.doi.org/10.3390/molecules28207163

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