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Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics

Ion implantation is a key capability for the semiconductor industry. As devices shrink, novel materials enter the manufacturing line, and quantum technologies transition to being more mainstream. Traditional implantation methods fall short in terms of energy, ion species, and positional precision. H...

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Autores principales: Titze, Michael, Poplawsky, Jonathan D., Kretschmer, Silvan, Krasheninnikov, Arkady V., Doyle, Barney L., Bielejec, Edward S., Hobler, Gerhard, Belianinov, Alex
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10609604/
https://www.ncbi.nlm.nih.gov/pubmed/37893321
http://dx.doi.org/10.3390/mi14101884
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author Titze, Michael
Poplawsky, Jonathan D.
Kretschmer, Silvan
Krasheninnikov, Arkady V.
Doyle, Barney L.
Bielejec, Edward S.
Hobler, Gerhard
Belianinov, Alex
author_facet Titze, Michael
Poplawsky, Jonathan D.
Kretschmer, Silvan
Krasheninnikov, Arkady V.
Doyle, Barney L.
Bielejec, Edward S.
Hobler, Gerhard
Belianinov, Alex
author_sort Titze, Michael
collection PubMed
description Ion implantation is a key capability for the semiconductor industry. As devices shrink, novel materials enter the manufacturing line, and quantum technologies transition to being more mainstream. Traditional implantation methods fall short in terms of energy, ion species, and positional precision. Here, we demonstrate 1 keV focused ion beam Au implantation into Si and validate the results via atom probe tomography. We show the Au implant depth at 1 keV is 0.8 nm and that identical results for low-energy ion implants can be achieved by either lowering the column voltage or decelerating ions using bias while maintaining a sub-micron beam focus. We compare our experimental results to static calculations using SRIM and dynamic calculations using binary collision approximation codes TRIDYN and IMSIL. A large discrepancy between the static and dynamic simulation is found, which is due to lattice enrichment with high-stopping-power Au and surface sputtering. Additionally, we demonstrate how model details are particularly important to the simulation of these low-energy heavy-ion implantations. Finally, we discuss how our results pave a way towards much lower implantation energies while maintaining high spatial resolution.
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spelling pubmed-106096042023-10-28 Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics Titze, Michael Poplawsky, Jonathan D. Kretschmer, Silvan Krasheninnikov, Arkady V. Doyle, Barney L. Bielejec, Edward S. Hobler, Gerhard Belianinov, Alex Micromachines (Basel) Article Ion implantation is a key capability for the semiconductor industry. As devices shrink, novel materials enter the manufacturing line, and quantum technologies transition to being more mainstream. Traditional implantation methods fall short in terms of energy, ion species, and positional precision. Here, we demonstrate 1 keV focused ion beam Au implantation into Si and validate the results via atom probe tomography. We show the Au implant depth at 1 keV is 0.8 nm and that identical results for low-energy ion implants can be achieved by either lowering the column voltage or decelerating ions using bias while maintaining a sub-micron beam focus. We compare our experimental results to static calculations using SRIM and dynamic calculations using binary collision approximation codes TRIDYN and IMSIL. A large discrepancy between the static and dynamic simulation is found, which is due to lattice enrichment with high-stopping-power Au and surface sputtering. Additionally, we demonstrate how model details are particularly important to the simulation of these low-energy heavy-ion implantations. Finally, we discuss how our results pave a way towards much lower implantation energies while maintaining high spatial resolution. MDPI 2023-09-30 /pmc/articles/PMC10609604/ /pubmed/37893321 http://dx.doi.org/10.3390/mi14101884 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Titze, Michael
Poplawsky, Jonathan D.
Kretschmer, Silvan
Krasheninnikov, Arkady V.
Doyle, Barney L.
Bielejec, Edward S.
Hobler, Gerhard
Belianinov, Alex
Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics
title Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics
title_full Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics
title_fullStr Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics
title_full_unstemmed Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics
title_short Measurement and Simulation of Ultra-Low-Energy Ion–Solid Interaction Dynamics
title_sort measurement and simulation of ultra-low-energy ion–solid interaction dynamics
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10609604/
https://www.ncbi.nlm.nih.gov/pubmed/37893321
http://dx.doi.org/10.3390/mi14101884
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