Rearrangement of a carboxy-substituted spiro[4.4]nonatriene to annulated fulvenes through a Pd(ii)-mediated 1,5-vinyl shift

A novel synthesis of aryl-substituted, enantioenriched fulvenes from an oxidative Heck cascade and rearrangement of a carboxy-substituted spiro[4.4]nonatriene is disclosed. Mechanistic investigations with density functional theory (DFT) calculations and empirical results support the net transformati...

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Detalles Bibliográficos
Autores principales: Goyal, Karan, Kukier, Garrett A., Chen, Xiangyang, Turlik, Aneta, Houk, K. N., Sarpong, Richmond
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619539/
https://www.ncbi.nlm.nih.gov/pubmed/37920349
http://dx.doi.org/10.1039/d3sc03222a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619539/
https://www.ncbi.nlm.nih.gov/pubmed/37920349
http://dx.doi.org/10.1039/d3sc03222a

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