Structural distortion by alkali metal cations modulates the redox and electronic properties of Ce(3+) imidophosphorane complexes

A series of Ce(3+) complexes with counter cations ranging from Li to Cs are presented. Cyclic voltammetry data indicate a significant dependence of the oxidation potential on the alkali metal identity. Analysis of the single-crystal X-ray diffraction data indicates that the degree of structural dist...

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Detalles Bibliográficos
Autores principales: Boggiano, Andrew C., Studvick, Chad M., Steiner, Alexander, Bacsa, John, Popov, Ivan A., La Pierre, Henry S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619540/
https://www.ncbi.nlm.nih.gov/pubmed/37920331
http://dx.doi.org/10.1039/d3sc04262f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619540/
https://www.ncbi.nlm.nih.gov/pubmed/37920331
http://dx.doi.org/10.1039/d3sc04262f

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