Base-mediated C–B bond activation of benzylic boronate for the rapid construction of β-silyl/boryl functionalized 1,1-diarylalkanes from aromatic alkenes

The effect of (t)BuOK on the existing state of benzylic boronates in the solution phase has been investigated in detail by NMR analysis and DFT calculations. It was determined that simply using an excess of (t)BuOK (2.0 equivalents) can result in the full deborylation of benzylic boronates to afford...

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Detalles Bibliográficos
Autores principales: Gao, Liuzhou, Liang, Xinyi, He, Linke, Li, Guoao, Chen, Shengda, Cao, Jia, Ma, Jing, Wang, Guoqiang, Li, Shuhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619622/
https://www.ncbi.nlm.nih.gov/pubmed/37920335
http://dx.doi.org/10.1039/d3sc03666a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619622/
https://www.ncbi.nlm.nih.gov/pubmed/37920335
http://dx.doi.org/10.1039/d3sc03666a

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