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New insights into H(2) activation by intramolecular frustrated Lewis pairs based on aminoboranes: the local electrophilicity index of boron as a suitable indicator to tune the reversibility of the process
A large set of intramolecular aminoborane-based FLPs was studied employing density functional theory in the H(2) activation process to analyze how the acidity and basicity of boron and nitrogen atoms, respectively, affect the reversibility of the process. Three different linkers were employed, keepi...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10619628/ https://www.ncbi.nlm.nih.gov/pubmed/37920343 http://dx.doi.org/10.1039/d3sc03992g |