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Cr(II) and Cr(III) NCN pincer complexes: synthesis, structure, and catalytic reactivity

The synthesis, characterization, and reactivity of several new Cr(II) and Cr(III) complexes featuring an NCN pincer ligand with an arene backbone connected to amine donors NEt(2) and NiPr(2) via CH(2)-linkers is described. Reacting the in situ lithiated ligand precursor N(C–Br)N(CH2)-Et with [CrCl(3...

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Detalles Bibliográficos
Autores principales: Käfer, Matthias G., Eder, Wolfgang, Pecak, Jan, Stöger, Berthold, Pignitter, Marc, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10620270/
https://www.ncbi.nlm.nih.gov/pubmed/37927401
http://dx.doi.org/10.1007/s00706-023-03128-6