Solvothermal synthesis of cobalt PCP pincer complexes from [Co(2)(CO)(8)]

Treatment of [Co(2)(CO)(8)] with the ipso-substituted P(C-X)P(Y) ligands (X = Br, Cl; R = iPr, tBu) bearing Y = NH and CH(2) linkers under solvothermal conditions affords the five-coordinate Co(I) and Co(III) complexes [Co(I)(PCP(Y)-R)(CO)(2)] and [Co(III)(PCP(Y)-R)X(2)]. The later are paramagnetic...

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Detalles Bibliográficos
Autores principales: Schratzberger, Heiko, Himmelbauer, Daniel, Eder, Wolfgang, Weiser, Michael, Stöger, Berthold, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2023
Materias:
Original Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10620272/
https://www.ncbi.nlm.nih.gov/pubmed/37927400
http://dx.doi.org/10.1007/s00706-023-03123-x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10620272/
https://www.ncbi.nlm.nih.gov/pubmed/37927400
http://dx.doi.org/10.1007/s00706-023-03123-x

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