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Solvothermal synthesis of cobalt PCP pincer complexes from [Co(2)(CO)(8)]
Treatment of [Co(2)(CO)(8)] with the ipso-substituted P(C-X)P(Y) ligands (X = Br, Cl; R = iPr, tBu) bearing Y = NH and CH(2) linkers under solvothermal conditions affords the five-coordinate Co(I) and Co(III) complexes [Co(I)(PCP(Y)-R)(CO)(2)] and [Co(III)(PCP(Y)-R)X(2)]. The later are paramagnetic...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Vienna
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10620272/ https://www.ncbi.nlm.nih.gov/pubmed/37927400 http://dx.doi.org/10.1007/s00706-023-03123-x |