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Conversion of a UO(2)(2+) Precursor to UH(+) and U(+) Using Tandem Mass Spectrometry to Remove Both “yl” Oxo Ligands

[Image: see text] Multiple-stage collision-induced dissociation (CID) of a uranyl propiolate cation, [UO(2)(O(2)C–C≡CH)](+), can be used to prepare the U-methylidyne species [O=U≡CH](+) [J. Am. Soc. Mass Spectrom.2019, 30, 796–805]. Here, we report that CID of [O=U≡CH](+) causes elimination of CO to...

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Detalles Bibliográficos
Autores principales: Terhorst, Justin G., Corcovilos, Theodore A., van Stipdonk, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10623558/
https://www.ncbi.nlm.nih.gov/pubmed/37843495
http://dx.doi.org/10.1021/jasms.3c00260