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Conversion of a UO(2)(2+) Precursor to UH(+) and U(+) Using Tandem Mass Spectrometry to Remove Both “yl” Oxo Ligands
[Image: see text] Multiple-stage collision-induced dissociation (CID) of a uranyl propiolate cation, [UO(2)(O(2)C–C≡CH)](+), can be used to prepare the U-methylidyne species [O=U≡CH](+) [J. Am. Soc. Mass Spectrom.2019, 30, 796–805]. Here, we report that CID of [O=U≡CH](+) causes elimination of CO to...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10623558/ https://www.ncbi.nlm.nih.gov/pubmed/37843495 http://dx.doi.org/10.1021/jasms.3c00260 |