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Access to unsaturated bicyclic lactones by overriding conventional C(sp(3))–H site selectivity

Transition metal catalysis plays a pivotal role in transforming unreactive C–H bonds. However, regioselective activation of distal aliphatic C–H bonds poses a tremendous challenge, particularly in the absence of directing templates. Activation of a methylene C–H bond in the presence of methyl C–H is...

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Detalles Bibliográficos
Autores principales: Das, Jayabrata, Ali, Wajid, Ghosh, Animesh, Pal, Tanay, Mandal, Astam, Teja, Chitrala, Dutta, Suparna, Pothikumar, Rajagopal, Ge, Haibo, Zhang, Xinglong, Maiti, Debabrata
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10624629/
https://www.ncbi.nlm.nih.gov/pubmed/37563324
http://dx.doi.org/10.1038/s41557-023-01295-x