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Access to unsaturated bicyclic lactones by overriding conventional C(sp(3))–H site selectivity
Transition metal catalysis plays a pivotal role in transforming unreactive C–H bonds. However, regioselective activation of distal aliphatic C–H bonds poses a tremendous challenge, particularly in the absence of directing templates. Activation of a methylene C–H bond in the presence of methyl C–H is...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10624629/ https://www.ncbi.nlm.nih.gov/pubmed/37563324 http://dx.doi.org/10.1038/s41557-023-01295-x |