Variable Ca‐C(aryl) Hapticity and its Consequences in Arylcalcium Dimers

The dimeric β‐diketiminato calcium hydride, [((Dipp)BDI)CaH](2) ((Dipp)BDI = HC{(Me)CN‐2,6‐i‐Pr(2)C(6)H(3)}(2)), reacts with ortho‐, meta‐ or para‐tolyl mercuric compounds to afford hydridoarylcalcium compounds, [((Dipp)BDI)(2)Ca(2)(μ‐H)(μ‐o‐,m‐,p‐tolyl)], in which dimer propagation occurs either vi...

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Detalles Bibliográficos
Autores principales: Pearce, Kyle G., Dinoi, Chiara, Schwamm, Ryan J., Maron, Laurent, Mahon, Mary F., Hill, Michael S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2023
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10625118/
https://www.ncbi.nlm.nih.gov/pubmed/37715248
http://dx.doi.org/10.1002/advs.202304765

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10625118/
https://www.ncbi.nlm.nih.gov/pubmed/37715248
http://dx.doi.org/10.1002/advs.202304765

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