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Variable Ca‐C(aryl) Hapticity and its Consequences in Arylcalcium Dimers
The dimeric β‐diketiminato calcium hydride, [((Dipp)BDI)CaH](2) ((Dipp)BDI = HC{(Me)CN‐2,6‐i‐Pr(2)C(6)H(3)}(2)), reacts with ortho‐, meta‐ or para‐tolyl mercuric compounds to afford hydridoarylcalcium compounds, [((Dipp)BDI)(2)Ca(2)(μ‐H)(μ‐o‐,m‐,p‐tolyl)], in which dimer propagation occurs either vi...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10625118/ https://www.ncbi.nlm.nih.gov/pubmed/37715248 http://dx.doi.org/10.1002/advs.202304765 |