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Synthesis and crystal structure of 2-(anthracen-9-yl)-1-(tert-butyl­dimethyl­sil­yl)-3,6-di­hydro-1λ(4),2λ(4)-aza­borinine

The title compound, C(24)H(30)BNSi (I), is an asymmetric 1,2,3,6-tetra­hydro-1,2-aza­borinine consisting of a BN-substituted cyclo­hexa­diene analog with a B-anthracenyl substituent. A ring-closing metathesis with subsequent substitution of the obtained BCl 1,2-aza­borinine using anthracenyl lithium...

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Detalles Bibliográficos
Autores principales: Gliese, Philipp J., Appiarius, Yannik, Scheele, Tarek, Lork, Enno, Neudecker, Tim, Staubitz, Anne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10626957/
https://www.ncbi.nlm.nih.gov/pubmed/37936862
http://dx.doi.org/10.1107/S2056989023008381