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Selective Transfer Semihydrogenation of Alkynes Catalyzed by an Iron PCP Pincer Alkyl Complex
[Image: see text] Two bench-stable Fe(II) alkyl complexes [Fe(κ(3)PCP-PCP-iPr)(CO)(2)(R)] (R = CH(2)CH(2)CH(3), CH(3)) were obtained by the treatment of [Fe(κ(3)PCP-PCP-iPr)(CO)(2)(H)] with NaNH(2) and subsequent addition of CH(3)CH(2)CH(2)Br and CH(3)I, respectively. The reaction proceeds via the a...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10629171/ https://www.ncbi.nlm.nih.gov/pubmed/37942266 http://dx.doi.org/10.1021/acscatal.3c04156 |