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Selective Transfer Semihydrogenation of Alkynes Catalyzed by an Iron PCP Pincer Alkyl Complex

[Image: see text] Two bench-stable Fe(II) alkyl complexes [Fe(κ(3)PCP-PCP-iPr)(CO)(2)(R)] (R = CH(2)CH(2)CH(3), CH(3)) were obtained by the treatment of [Fe(κ(3)PCP-PCP-iPr)(CO)(2)(H)] with NaNH(2) and subsequent addition of CH(3)CH(2)CH(2)Br and CH(3)I, respectively. The reaction proceeds via the a...

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Detalles Bibliográficos
Autores principales:	Schratzberger, Heiko, Stöger, Berthold, Veiros, Luis F., Kirchner, Karl
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10629171/ https://www.ncbi.nlm.nih.gov/pubmed/37942266 http://dx.doi.org/10.1021/acscatal.3c04156

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