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Trace Water Changes Metal Ion Speciation in Deep Eutectic Solvents: Ce(3+) Solvation and Nanoscale Water Clustering in Choline Chloride–Urea–Water Mixtures

[Image: see text] Eutectic mixtures of choline chloride, urea, and water in deep eutectic solvent (DES)/water molar hydration ratios (w) of 2, 5, and 10, with dissolved cerium salt, were measured using neutron diffraction with isotopic substitution. Structures were modeled using empirical potential...

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Detalles Bibliográficos
Autores principales: Hammond, Oliver S., Bathke, Elly K., Bowron, Daniel T., Edler, Karen J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10630939/
https://www.ncbi.nlm.nih.gov/pubmed/37862703
http://dx.doi.org/10.1021/acs.inorgchem.3c02205