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Vesicles, fibres, films and crystals: A low-molecular-weight-gelator [Au(6-thioguanosine)(2)]Cl which exhibits a co-operative anion-induced transition from vesicles to a fibrous metallo-hydrogel

We describe a simple coordination compound of Au(i) and 6-thioguanosine, [Au(6-tGH)(2)]Cl, that has a rich self-assembly chemistry. In aqueous solution, the discrete complex assembles into a supramolecular fibre and forms a luminescent hydrogel at concentrations above about 1 mM. Below this concentr...

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Detalles Bibliográficos
Autores principales: McGarry, Liam F., El-Zubir, Osama, Waddell, Paul G., Cucinotta, Fabio, Houlton, Andrew, Horrocks, Benjamin R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10630954/
https://www.ncbi.nlm.nih.gov/pubmed/37873806
http://dx.doi.org/10.1039/d3sm01006f