Influence of Ring Strain on the Formation of Rearrangement vs Cyclization Isotwistane Products in the Acyl Radical Reaction of Bicyclo[2.2.2]octanone

[Image: see text] An acyl radical reaction of bicyclo[2.2.2]octenone to yield either rearranged or cyclized isotwistane products is described. The influence of ring strain on the reaction was demonstrated by alternating the sizes of the fused ring in the starting material. DFT calculations showed th...

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Detalles Bibliográficos
Autores principales: Chen, Chih-Ming, Lin, Sheng-Kuo, Hsieh, Chi-Tien, Reddy, Julakanti Satyanarayana, Teoh, Yi Ning, Cheng, Mu-Jeng, Hsieh, Hsing-Pang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10630961/
https://www.ncbi.nlm.nih.gov/pubmed/37738398
http://dx.doi.org/10.1021/acs.orglett.3c02374

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10630961/
https://www.ncbi.nlm.nih.gov/pubmed/37738398
http://dx.doi.org/10.1021/acs.orglett.3c02374

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