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Variation from closed-shell to open shell electronic structures in oligothiophene bis(dioxolene) complexes
A series of oligothiophene bis(dioxolene) complexes, SQ–Th(n)–SQ (SQ = S = ½Tp(Cum,Me)Zn(II)(3-tert-butyl-orthosemiquinonate); Tp(Cum,Me) = tris(5-cumenyl-3-methylpyrazolyl)borate anion) have been synthesized, structurally characterized, and studied as a function of the number of thiophene bridging...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631215/ https://www.ncbi.nlm.nih.gov/pubmed/37969598 http://dx.doi.org/10.1039/d3sc02341a |