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Variation from closed-shell to open shell electronic structures in oligothiophene bis(dioxolene) complexes

A series of oligothiophene bis(dioxolene) complexes, SQ–Th(n)–SQ (SQ = S = ½Tp(Cum,Me)Zn(II)(3-tert-butyl-orthosemiquinonate); Tp(Cum,Me) = tris(5-cumenyl-3-methylpyrazolyl)borate anion) have been synthesized, structurally characterized, and studied as a function of the number of thiophene bridging...

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Detalles Bibliográficos
Autores principales: Miller, Paul D., Shultz, David A., Mengell, Joshua, Kirk, Martin L., Wojtas, Lukasz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631215/
https://www.ncbi.nlm.nih.gov/pubmed/37969598
http://dx.doi.org/10.1039/d3sc02341a