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Cooperative dihydrogen activation with unsupported uranium–metal bonds and characterization of a terminal U(iv) hydride
Cooperative chemistry between two or more metal centres can show enhanced reactivity compared to the monometallic fragments. Given the paucity of actinide–metal bonds, especially those with group 13, we targeted uranium(iii)–aluminum(i) and –gallium(i) complexes as we envisioned the low-valent oxida...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631237/ https://www.ncbi.nlm.nih.gov/pubmed/37969582 http://dx.doi.org/10.1039/d3sc04857h |