Unravelling strong temperature-dependence of J(HD) in transition metal hydrides: solvation and non-covalent interactions versus temperature-elastic H–H bonds

A number of transition metal hydrides reveal intriguing temperature-dependent J(HD) in their deuterated derivatives and possibly the temperature dependent hydrogen–hydrogen distance (r(H–H)) as well. Previously, theoretical studies rationalized J(HD) and r(H–H) changes in such compounds through a “t...

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Detalles Bibliográficos
Autores principales: Polukeev, Alexey V., Capelli, Silvia C., Wendt, Ola F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631239/
https://www.ncbi.nlm.nih.gov/pubmed/37969611
http://dx.doi.org/10.1039/d3sc04197b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631239/
https://www.ncbi.nlm.nih.gov/pubmed/37969611
http://dx.doi.org/10.1039/d3sc04197b

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