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Unravelling strong temperature-dependence of J(HD) in transition metal hydrides: solvation and non-covalent interactions versus temperature-elastic H–H bonds
A number of transition metal hydrides reveal intriguing temperature-dependent J(HD) in their deuterated derivatives and possibly the temperature dependent hydrogen–hydrogen distance (r(H–H)) as well. Previously, theoretical studies rationalized J(HD) and r(H–H) changes in such compounds through a “t...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631239/ https://www.ncbi.nlm.nih.gov/pubmed/37969611 http://dx.doi.org/10.1039/d3sc04197b |