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Organocatalytic atroposelective synthesis of axially chiral N,N′-pyrrolylindoles via de novo indole formation
The first organocatalytic atroposelective synthesis of axially chiral N,N′-pyrrolylindoles based on o-alkynylanilines was successfully established via de novo indole formation catalyzed by chiral phosphoric acid (CPA). This new synthetic strategy introduced CPA-catalyzed asymmetric 5-endo-dig cycliz...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631393/ https://www.ncbi.nlm.nih.gov/pubmed/37969599 http://dx.doi.org/10.1039/d3sc03686c |