Tellurolate: an effective Te-atom transfer reagent to prepare the triad of group 5 metal bis(tellurides)

We show in this work how lithium tellurolate Li(X)(n)TeCH(2)SiMe(3) (X = THF, n = 1, 1; X = 12-crown-4, n = 2, 2), can serve as an effective Te-atom transfer reagent to all group 5 transition metal halide precursors irrespective of the oxidation state. Mononuclear and bis(telluride) complexes, namel...

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Detalles Bibliográficos
Autores principales: Senthil, Shuruthi, Kwon, Seongyeon, Kong, Richard Y., MacMillan, Samantha N., Zatsepin, Pavel, Gau, Michael R., Carroll, Patrick J., Baik, Mu-Hyun, Lancaster, Kyle M., Mindiola, Daniel J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631448/
https://www.ncbi.nlm.nih.gov/pubmed/37969607
http://dx.doi.org/10.1039/d3sc03470d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10631448/
https://www.ncbi.nlm.nih.gov/pubmed/37969607
http://dx.doi.org/10.1039/d3sc03470d

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